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Registro completo
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Biblioteca (s) : |
INIA Las Brujas. |
Fecha : |
12/11/2015 |
Actualizado : |
09/10/2019 |
Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
Autor : |
BESIL, N.; PÉREZ-PARADA, A.; CESIO, V.; VARELA, P.; RIVAS, F.; HEINZEN, H. |
Afiliación : |
NATALIA BESIL, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química; ANDRÉS PÉREZ-PARADA, Universidad de la República (UdelaR)/ Facultad de Química; VERÓNICA CESIO, Universidad de la República (UdelaR)/ Facultad de Química; PABLO NICOLAS VARELA PESSOLANO, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; CARLOS FERNANDO RIVAS GRELA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; HORACIO HEINZEN, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química. |
Título : |
Degradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. |
Fecha de publicación : |
2015 |
Fuente / Imprenta : |
Food Chemistry, 2016, v.194, p. 1132-1137. |
ISSN : |
0308-8146 |
DOI : |
10.1016/j.foodchem.2015.08.111 |
Idioma : |
Inglés |
Notas : |
Article history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015.
Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650). |
Contenido : |
ABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different.
Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments.
2015 Elsevier Ltd. All rights reserved. MenosABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazali... Presentar Todo |
Palabras claves : |
Degradation; Postharvest fungicides. |
Thesagro : |
CITRUS; FUNGICIDAS; TECNICA POSTCOSECHA. |
Asunto categoría : |
H20 Enfermedades de las plantas |
Marc : |
LEADER 02850naa a2200277 a 4500 001 1053857 005 2019-10-09 008 2015 bl uuuu u00u1 u #d 022 $a0308-8146 024 7 $a10.1016/j.foodchem.2015.08.111$2DOI 100 1 $aBESIL, N. 245 $aDegradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. 260 $c2015 500 $aArticle history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015. Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650). 520 $aABSTRACT. The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially. Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different. Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments. 2015 Elsevier Ltd. All rights reserved. 650 $aCITRUS 650 $aFUNGICIDAS 650 $aTECNICA POSTCOSECHA 653 $aDegradation 653 $aPostharvest fungicides 700 1 $aPÉREZ-PARADA, A. 700 1 $aCESIO, V. 700 1 $aVARELA, P. 700 1 $aRIVAS, F. 700 1 $aHEINZEN, H. 773 $tFood Chemistry, 2016$gv.194, p. 1132-1137.
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1. | | ASPLANATO, G. Control biológico aplicado. (Capítulo V) In: ASPLANATO, G. (Ed.). El minador de la hoja de los cítricos, Phyllocnistis citrella (Lepidotera: gracillariidae): Bioecología y control biológico. Montevideo (Uruguay): INIA, 2009. p. 39-44 (Serie FPTA-INIA ; 24)Tipo: Capítulo en Libro Técnico-Científico |
Biblioteca(s): INIA Las Brujas; INIA Tacuarembó. |
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2. | | ASPLANATO, G. Biología, ecología y enemigos naturales. (Capítulo III) In: ASPLANATO, G. (Ed.). El minador de la hoja de los cítricos, Phyllocnistis citrella (Lepidotera: gracillariidae): Bioecología y control biológico. Montevideo (Uruguay): INIA, 2009. p. 23-32 (Serie FPTA-INIA ; 24)Tipo: Capítulo en Libro Técnico-Científico |
Biblioteca(s): INIA Las Brujas; INIA Tacuarembó. |
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4. | | ASPLANATO, G. Reconocimiento, daños e importancia económica. (Capítulo II) In: ASPLANATO, G. (Ed.). El minador de la hoja de los cítricos, Phyllocnistis citrella (Lepidotera: gracillariidae): Bioecología y control biológico. Montevideo (Uruguay): INIA, 2009. p. 13-22 (Serie FPTA-INIA ; 24)Tipo: Capítulo en Libro Técnico-Científico |
Biblioteca(s): INIA Las Brujas; INIA Tacuarembó. |
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14. | | SCATONI, I.; ASPLANATO, G.; BENTANCOURT, C.; PAZOS, J.; SOLER, R.; FRANCO, J.; PAULLIER, J. Dinámica de los distintos estados del minador de los brotes de los cítricos, (Phyllocnistis citrella Stainton, Lep. Gracillariidae) en relación al tamaño de las hojas. In: INIA Salto Grande; Universidad de la República (UdelaR)/ Facultad de Agronomía; MGAP/Plan Citrícola. Minador de las hojas de los cítricos: Phyllocnistis citrella Stainton. Avances de investigación 1997-1999. Salto (UY): INIA Salto Grande, 1999. p. 27-31. (INIA Serie Actividades de Difusión; 203) Financiaron este trabajo la Comisión Sectorial de Investigación Científica (Universidad de la República) y las instituciones involucradas.Biblioteca(s): INIA Salto Grande. |
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15. | | SCATONI, I.; ASPLANATO, G.; BENTANCOURT, C.; PAZOS, J.; SOLER, R.; FRANCO, J.; PAULLIER, J. Dinámica poblacional del minador de los brotes de los cítricos, (Phyllocnistis citrella Stainton, Lep. Gracillariidae). In: INIA Salto Grande; Universidad de la República (UdelaR)/ Facultad de Agronomía; MGAP/Plan Citrícola. Minador de las hojas de los cítricos: Phyllocnistis citrella Stainton. Avances de investigación 1997-1999. Salto (UY): INIA Salto Grande, 1999. p. 17-26. (INIA Serie Actividades de Difusión; 203) Financiaron este trabajo la Comisión Sectorial de Investigación Científica (Universidad de la República) y las instituciones involucradas.Biblioteca(s): INIA Salto Grande. |
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18. | | BUENAHORA, J.; BENTANCOURT, C.; SCATONI, I.; ASPLANATO, G.; PAULLIER, J.; PAZOS, J.; PINTOS, J.; GONZÁLEZ, A. Enemigos naturales del minador de las hojas de los cítricos, Phyllocnistis citrella Stainton (Lep. Gracillaridae). ln: Congreso Nacional de Horticultura, 8.; Seminario Regional de Frutilla, 2001, Salto, Uruguay. Resúmenes. Montevideo (Uruguay): SUH; INIA, 2001. p. 84 Sociedad Uruguaya de Horticultura; Instituto Nacional de Investigación Agropecuaria, Uruguay.Biblioteca(s): INIA Las Brujas; INIA Salto Grande; INIA Tacuarembó; INIA Treinta y Tres. |
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19. | | ASPLANATO, G.; PAZOS, J.; BUENAHORA, J.; AMUEDO, S.; RUBIO, L.; FRANCO, J. El psílido asiático de los cítricos, Diaphorina citri (HEMIPTER: PSYLLIDAE): primeros estudios bioecológicos en Uruguay Montevideo (UY): INIA, 2011. 46 p. (Serie FPTA-INIA; 28) "Proyecto FPTA 230: "Diaphorina citri Kuwayama (Hemiptera: Psyllidae), vector de Candidatus Liberibacter spp., organismo causal del Huanglongbing de los cítricos, contribución al desarrollo del manejo integrado de la plaga". Período de...Biblioteca(s): INIA Las Brujas; INIA Tacuarembó. |
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20. | | SCATONI, I.; ASPLANATO, G.; BENTANCOURT, C.; PAZOS, J.; SOLER, R.; GONZÁLEZ, A.; NOGUEIRA, M.; FRANCO, J.; PAULLIER, J. Control químico del minador de los brotes de los cítricos, (Phyllocnistits citrella Stainton, Lep. Gracillariidae). In: INIA Salto Grande; Universidad de la República (UdelaR)/ Facultad de Agronomía; MGAP/Plan Citrícola. Minador de las hojas de los cítricos: Phyllocnistis citrella Stainton. Avances de investigación 1997-1999. Salto (UY): INIA Salto Grande, 1999. p. 32-37. (INIA Serie Actividades de Difusión; 203) Financiaron este trabajo las Empresas de Agroquímicos, Facultad de Agronomía e INIA.Biblioteca(s): INIA Salto Grande. |
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Registros recuperados : 21 | |
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