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Registro completo
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Biblioteca (s) : |
INIA La Estanzuela; INIA Las Brujas; INIA Treinta y Tres. |
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Fecha : |
14/02/2022 |
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Actualizado : |
14/03/2022 |
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Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
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Autor : |
GRAHMANN, K.; TERRA, J.A.; ELLERBROCK, R.; RUBIO, V.; BARRO, R.; CAMAÑO, A.; QUINCKE, A. |
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Afiliación : |
KATHRIN GRAHMANN, Leibniz Centre for Agricultural Landscape Research (ZALF); Eberswalder Str.84, 15374 Müncheberg, Germany; JOSÉ ALFREDO TERRA FERNÁNDEZ, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; RUTH ELLERBROCK, Leibniz Centre for Agricultural Landscape Research (ZALF); Eberswalder Str.84, 15374 Müncheberg; VALENTINA RUBIO DELLEPIANE, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; RAQUEL BARRO, Postdoctoral Scholarship ANII (National agency of innovation and research, Uruguay); ALEJANDRO CAMAÑO, Service Unit for the Evaluation of Quality and Environmental Control, Department of Environmental Development, Intendancy of Montevideo, Uruguay; JUAN ANDRES QUINCKE WALDEN, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay. |
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Título : |
Data accuracy and method validation of chemical soil properties in long-term experiments: Standard operating procedures for a non-certified soil laboratory in Latin America. |
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Fecha de publicación : |
2022 |
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Fuente / Imprenta : |
Geoderma Regional, 2022. Volume 28, Article number e00487. OPEN ACCESS. doi: https://doi.org/10.1016/j.geodrs.2022.e00487 |
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DOI : |
10.1016/j.geodrs.2022.e00487 |
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Idioma : |
Inglés |
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Notas : |
Article history: Received 9 May 2021, Revised 20 December 2021, Accepted 2 February 2022, Available online 6 February 2022. |
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Contenido : |
ABSTRACT.- Long-term agricultural experiments (LTE) are essential to detect cumulative treatment effects on soil properties and to design sustainable production systems. However, to ensure high quality of long-term soil data and their correct interpretation, several analytical issues regarding the accuracy and analytical laboratory bias need to be considered. This paper aims to (1) evaluate laboratory precision and trueness of analytical soil data for the evaluation of long-term trends in LTE and to (2) assess the limitations and challenges for non-certified soil laboratories that might compromise the quality of analytical soil data. A data set of internal reference soil materials (IRM) collected over 16?years and interlaboratory data from eleven years were analyzed to verify method precision, trueness, and the subsequent long-term dataset reliability for several soil quality parameters: organic carbon (SOC, determined either by wet or dry combustion), pH (water), extractable phosphorous (either Bray I or citric acid; Bray-P or citric acid-P), and exchangeable potassium (Kexch). Results showed that IRM used by the laboratory were homogenous in terms of physical and chemical composition and appropriate to confirm the precision of long-term soil survey data. The relative standard deviation for repeatability and reproducibility (RSDR) ranged from 1.5% for SOC by wet combustion to 9.5% for citric acid-P. HorRat values (the ratio of the estimated standard deviations of reproducibility and the repeatability found for individual analytical procedures) for all chemical soil properties were within the acceptable ranges of <2.0. Interlaboratory trials for soil pH and SOC showed tolerable standard Z-Scores under 2.0 (Z-Score, calculated from the difference between laboratory results and the assigned value divided by the standard deviation), verifying the trueness of data. The results of this study reinforce the validity of analytical soil data originating from the non-certified laboratory in Uruguay obtaining both precise and true soil quality data over a long period of time for most soil analytes. Nevertheless, the analytical flaws in LTE soil monitoring were revealed and can only be minimized in ongoing and future studies through the inclusion of certified reference material. These recommendations should guide future research activities in LTE studies on analytical data quality management as a requirement for long-term soil monitoring. Finally, the paper proposes a proficiency testing procedure for soil laboratories to achieve and maintain high analytical quality for LTE soil research.
© 2022 The Authors. Published by Elsevier B.V. MenosABSTRACT.- Long-term agricultural experiments (LTE) are essential to detect cumulative treatment effects on soil properties and to design sustainable production systems. However, to ensure high quality of long-term soil data and their correct interpretation, several analytical issues regarding the accuracy and analytical laboratory bias need to be considered. This paper aims to (1) evaluate laboratory precision and trueness of analytical soil data for the evaluation of long-term trends in LTE and to (2) assess the limitations and challenges for non-certified soil laboratories that might compromise the quality of analytical soil data. A data set of internal reference soil materials (IRM) collected over 16?years and interlaboratory data from eleven years were analyzed to verify method precision, trueness, and the subsequent long-term dataset reliability for several soil quality parameters: organic carbon (SOC, determined either by wet or dry combustion), pH (water), extractable phosphorous (either Bray I or citric acid; Bray-P or citric acid-P), and exchangeable potassium (Kexch). Results showed that IRM used by the laboratory were homogenous in terms of physical and chemical composition and appropriate to confirm the precision of long-term soil survey data. The relative standard deviation for repeatability and reproducibility (RSDR) ranged from 1.5% for SOC by wet combustion to 9.5% for citric acid-P. HorRat values (the ratio of the estimated standard deviations of reproducib... Presentar Todo |
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Palabras claves : |
Data precision; Internal reference material; Repeatability; Reproducibility; Soil organic carbon; Trueness; URUGUAY. |
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Asunto categoría : |
P30 Ciencia del suelo y manejo del suelo |
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URL : |
https://www.sciencedirect.com/science/article/pii/S2352009422000074/pdf?md5=8d5a81ff8de54639cfdb18c6fdec1c4a&pid=1-s2.0-S2352009422000074-main.pdf
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Marc : |
LEADER 03790naa a2200301 a 4500
001 1062741
005 2022-03-14
008 2022 bl uuuu u00u1 u #d
024 7 $a10.1016/j.geodrs.2022.e00487$2DOI
100 1 $aGRAHMANN, K.
245 $aData accuracy and method validation of chemical soil properties in long-term experiments$bStandard operating procedures for a non-certified soil laboratory in Latin America.$h[electronic resource]
260 $c2022
500 $aArticle history: Received 9 May 2021, Revised 20 December 2021, Accepted 2 February 2022, Available online 6 February 2022.
520 $aABSTRACT.- Long-term agricultural experiments (LTE) are essential to detect cumulative treatment effects on soil properties and to design sustainable production systems. However, to ensure high quality of long-term soil data and their correct interpretation, several analytical issues regarding the accuracy and analytical laboratory bias need to be considered. This paper aims to (1) evaluate laboratory precision and trueness of analytical soil data for the evaluation of long-term trends in LTE and to (2) assess the limitations and challenges for non-certified soil laboratories that might compromise the quality of analytical soil data. A data set of internal reference soil materials (IRM) collected over 16?years and interlaboratory data from eleven years were analyzed to verify method precision, trueness, and the subsequent long-term dataset reliability for several soil quality parameters: organic carbon (SOC, determined either by wet or dry combustion), pH (water), extractable phosphorous (either Bray I or citric acid; Bray-P or citric acid-P), and exchangeable potassium (Kexch). Results showed that IRM used by the laboratory were homogenous in terms of physical and chemical composition and appropriate to confirm the precision of long-term soil survey data. The relative standard deviation for repeatability and reproducibility (RSDR) ranged from 1.5% for SOC by wet combustion to 9.5% for citric acid-P. HorRat values (the ratio of the estimated standard deviations of reproducibility and the repeatability found for individual analytical procedures) for all chemical soil properties were within the acceptable ranges of <2.0. Interlaboratory trials for soil pH and SOC showed tolerable standard Z-Scores under 2.0 (Z-Score, calculated from the difference between laboratory results and the assigned value divided by the standard deviation), verifying the trueness of data. The results of this study reinforce the validity of analytical soil data originating from the non-certified laboratory in Uruguay obtaining both precise and true soil quality data over a long period of time for most soil analytes. Nevertheless, the analytical flaws in LTE soil monitoring were revealed and can only be minimized in ongoing and future studies through the inclusion of certified reference material. These recommendations should guide future research activities in LTE studies on analytical data quality management as a requirement for long-term soil monitoring. Finally, the paper proposes a proficiency testing procedure for soil laboratories to achieve and maintain high analytical quality for LTE soil research. © 2022 The Authors. Published by Elsevier B.V.
653 $aData precision
653 $aInternal reference material
653 $aRepeatability
653 $aReproducibility
653 $aSoil organic carbon
653 $aTrueness
653 $aURUGUAY
700 1 $aTERRA, J.A.
700 1 $aELLERBROCK, R.
700 1 $aRUBIO, V.
700 1 $aBARRO, R.
700 1 $aCAMAÑO, A.
700 1 $aQUINCKE, A.
773 $tGeoderma Regional, 2022. Volume 28, Article number e00487. OPEN ACCESS. doi: https://doi.org/10.1016/j.geodrs.2022.e00487
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Registro original : |
INIA Las Brujas (LB) |
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| Registros recuperados : 10 | |
| 2. |  | PALLADINO, C.; PAREJA, L.; PEREYRA, S.; PÉREZ, C. Problems of pesticide residues in grains. [La problemática de los residuos de fitosanitarios en granos]. [Problemática dos resíduos de fitossanitários em grãos]. I Technical Conference of the Plant Protection Group - EEMAC. Agrociencia Uruguay, 2023, Vol.27 (Supplement), e1230. https://doi.org/10.31285/AGRO.27.1230 -- OPEN ACCESS. Article history: Received 24 Jul 2032; Accepted 25 Jul 2023; Published 11 Sep 2023. -- Editor: Horacio Silva, Universidad de la República, Facultad de Agronomía, Paysandú, Uruguay. -- Correspondence: Cintia Palladino,...| Tipo: Artículos en Revistas Indexadas Nacionales | Circulación / Nivel : Nacional - -- |
| Biblioteca(s): INIA Las Brujas. |
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| 3. | | PALLADINO, C.; PÉREZ, C.A.; PAREJA, L.; PÉREZ-PARADA. A.; FRANCO, J.; PEREYRA, S. Fungicide strategies for Ramularia Leaf Spot control recommended in Uruguay and its residues in barley grains. [Estrategias de fungicidas recomendadas para el control de ramulariosis en Uruguay y sus residuos en granos de cebada.]. [Estratégias de fungicidas para o controlo da ramulariose recomendadas no Uruguai e respectivos resíduos nos grãos de cevada.]. Section. Plant protection. Agrociencia Uruguay, 2024, Vol.28, e1262. https://doi.org/10.31285/AGRO.28.1262 -- OPEN ACCESS. Article history: Received 04 October 2023; Accepted 01 December 2023; Published 01 February 2024. -- Editor: María Inés Siri, Universidad de la República, Montevideo, Uruguay. -- Correspondence: Cintia Palladino, cpalladino@cup.edu.uy --...| Tipo: Artículos en Revistas Indexadas Nacionales | Circulación / Nivel : Nacional - -- |
| Biblioteca(s): INIA Las Brujas. |
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| 5. | | PALLADINO, C.; MUELA, A.; TABORDA, B.; PUIGVERT, F.; PÉREZ-PARADA, A.; COLAZZO, M.; PÉREZ, C. A.; PEREYRA, S.; PAREJA, L. Application of a straightforward Mmthodology by LC-QqQ-MS/MS and GC-MS to ensure food safety of barley and wheat grain. ACS Agricultural Science and Technology, 2022, Volume 2, Issue 2, Pages 371-380. doi: https://doi.org/10.1021/acsagscitech.1c00263 Article history: Received 29 November 2021; Accepted 24 February 2022; Revised 4 February 2022; Published online 16 March 2022; Published in issue 18 April 2022.
Corresponding author: Pareja, L.; Departamento de Química Del...| Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
| Biblioteca(s): INIA Las Brujas. |
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| 6. | | NIELL, S.; PAREJA, L.; ASTEGGIANTE, L.G.; ROEHRS, R.; PIZZUTTI, I.R.; GARCIA, C.; HEINZEN, H.; CESIO, M.V. Development of methods for multiresidue analysis of rice post-emergence herbicides in loam soil and their possible applications to soils of different composition. Journal of AOAC International, 2010, v. 93 no.2, p. 425-431. 2-s2.0-77952781014| Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : B - 1 |
| Biblioteca(s): INIA Las Brujas. |
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| 7. | | PAREJA, L.; COLAZZO, M.; PÉREZ-PARADA, A.; NIELL, S.; CARRASCO-LETELIER, L.; BESIL, N.; CESIO, M.V.; HEINZEN, H. Detection of pesticides in active and depopulated beehives in Uruguay International Journal of Environmental Research and Public Health, 2011, v. 8, n. 10, p. 3844-3858 OPEN ACCESS ARTICLE.| Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : B - 1 |
| Biblioteca(s): INIA La Estanzuela; INIA Las Brujas. |
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| 8. | | NIELL, S.; JESÚS, F.; PÉREZ, N.; PÉREZ, C.; PAREJA, L.; ABATTE, S.; CARRASCO-LETELIER, L.; DIAZ, S.; MENDOZA, Y.; CESIO, V.; HEINZEN, H. Neonicotinoids transference from the field to the hive by honey bees: Towards a pesticide residues biomonitor Science of the Total Environment, 2017, v. 581-582, p. 25-31 Article history: Received 3 October 2016 / Received in revised form 14 December 2016 / Accepted 2 January 2017 / Available online xxxx| Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
| Biblioteca(s): INIA La Estanzuela; INIA Las Brujas. |
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| 9. | | PÉREZ, A.; ALONSO, B.; ERNST, F.; RODRÍGUEZ, C.; CESIO, V.; HEINZEN, H.; COLAZZO, M.; PAREJA, L.; PEREIRA, A.; MÁRQUEZ, A.; ERRICO, E. Residuos de plaguicidas en compartimentos ambientales. Montevideo (UY): INIA, 2020. 30 p. (Serie FPTA-INIA; 90) Proyecto FPTA 324: "Estudio del impacto de las actuales prácticas agrícolas en los recursos hídricos del bajo Río Negro y Esteros de Farrapos.". Período de ejecución: Mayo 2014 - Junio 2017. Institución Ejecutora: Universidad de la...| Biblioteca(s): INIA Las Brujas. |
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| 10. | | PEREYRA, S.; CASTRO, M.; VERO, S.; SILVA, P.; CAL, A.; TISCORNIA, G.; GONZALEZ, N.; BENTOS, D.; ALVAREZ, W.; RABAZA, S.; SEVILLANO, L.; BRANCATTI, G.; FRANCIA, C.; RAFFO, M.A.; GERMAN, S.; PÉREZ, C.; GARMENDIA, G.; PAREJA, L.; RODRÍGUEZ, A.; PENDAS, C.; QUINCKE, M.; VÁZQUEZ, D.; RODRIGUEZ, M. Fusariosis de la espiga en trigo y micotoxinas asociadas: contribuyendo a reducir su riesgo. Cultivos. Revista INIA Uruguay, Diciembre 2023, no.75 p.54-58. (Revista INIA; 75).| Tipo: Artículos en Revistas Agropecuarias |
| Biblioteca(s): INIA Las Brujas. |
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| Registros recuperados : 10 | |
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