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 | Acceso al texto completo restringido a Biblioteca INIA Las Brujas. Por información adicional contacte bibliolb@inia.org.uy. |
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Biblioteca (s) : |
INIA Las Brujas. |
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Fecha : |
12/11/2015 |
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Actualizado : |
09/10/2019 |
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Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
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Autor : |
BESIL, N.; PÉREZ-PARADA, A.; CESIO, V.; VARELA, P.; RIVAS, F.; HEINZEN, H. |
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Afiliación : |
NATALIA BESIL, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química; ANDRÉS PÉREZ-PARADA, Universidad de la República (UdelaR)/ Facultad de Química; VERÓNICA CESIO, Universidad de la República (UdelaR)/ Facultad de Química; PABLO NICOLAS VARELA PESSOLANO, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; CARLOS FERNANDO RIVAS GRELA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; HORACIO HEINZEN, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química. |
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Título : |
Degradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. |
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Fecha de publicación : |
2015 |
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Fuente / Imprenta : |
Food Chemistry, 2016, v.194, p. 1132-1137. |
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ISSN : |
0308-8146 |
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DOI : |
10.1016/j.foodchem.2015.08.111 |
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Idioma : |
Inglés |
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Notas : |
Article history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015.
Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650). |
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Contenido : |
ABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different.
Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments.
2015 Elsevier Ltd. All rights reserved. MenosABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazali... Presentar Todo |
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Palabras claves : |
Degradation; Postharvest fungicides. |
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Thesagro : |
CITRUS; FUNGICIDAS; TECNICA POSTCOSECHA. |
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Asunto categoría : |
H20 Enfermedades de las plantas |
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Marc : |
LEADER 02850naa a2200277 a 4500
001 1053857
005 2019-10-09
008 2015 bl uuuu u00u1 u #d
022 $a0308-8146
024 7 $a10.1016/j.foodchem.2015.08.111$2DOI
100 1 $aBESIL, N.
245 $aDegradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C.
260 $c2015
500 $aArticle history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015. Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650).
520 $aABSTRACT. The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially. Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different. Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments. 2015 Elsevier Ltd. All rights reserved.
650 $aCITRUS
650 $aFUNGICIDAS
650 $aTECNICA POSTCOSECHA
653 $aDegradation
653 $aPostharvest fungicides
700 1 $aPÉREZ-PARADA, A.
700 1 $aCESIO, V.
700 1 $aVARELA, P.
700 1 $aRIVAS, F.
700 1 $aHEINZEN, H.
773 $tFood Chemistry, 2016$gv.194, p. 1132-1137.
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INIA Las Brujas (LB) |
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Registro completo
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Biblioteca (s) : |
INIA Las Brujas. |
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Fecha actual : |
31/01/2020 |
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Actualizado : |
31/01/2020 |
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Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
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Circulación / Nivel : |
B - 1 |
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Autor : |
SPOHR, R.B.; CARLESSO, R.; GARCIA, C.; GARCÍA PRÉCHAC, F.; GARCÍA PETILLO, M. |
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Afiliación : |
RENATO BEPPLER SPOHR, Centro de Ciências Agrária de Itaqui, Universidade Federal do Pampa (UNIPAMPA), Itaqui, RS, Brazil; REIMAR CARLESSO, Departamento de Engenharia Rural, Universidade Federal de Santa Maria (UFSM), Santa Maria, RS, Brazil; CLAUDIO CESAR GARCIA GALLARRETA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; FERNANDO GARCÍA PRÉCHAC, Faculdad de Agronomia, Universidad de la República, Montevideo, Uruguay; MARIO GARCÍA PETILLO, Faculdad de Agronomia, Universidad de la República, Montevideo, Uruguay. |
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Título : |
Runoff modeling from soil physical characteristics in different places in Uruguay. [Modelagem do escoamento superficial a partir das características físicas de alguns solos do Uruguai.] |
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Fecha de publicación : |
2009 |
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Fuente / Imprenta : |
Ciencia Rural, January 2009, Volume 39, Issue 1, January 2009, Pages 74-81. OPEN ACCESS. |
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ISSN : |
0103-8478 |
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DOI : |
10.1590/S0103-84782009000100012 |
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Idioma : |
Portugués |
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Notas : |
Article history: Recebido para publicação 11 Decembro 2007 / Aprovado em 20 Agosto 2008. |
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Contenido : |
ABSTRACT.
The objective of this research was to determinate and modeling the runoff for different soils classes based on different simulated rainfall intensities (30, 60 and 120mm h-1) in different soils in Uruguay. A portable rainfall simulator with multiple nozzles was used to simulate different rainfall intensities. On each soil was measured the initial time and rate of runoff, rainfall (total, duration and intensities), direction of slope, crop residue and cover percentage, soil densities (bulk and particle), soil porosity (bulk, macro and micro), textural fractions (clay, silt and sand), initial and saturated soil moisture. The runoff was estimated with Smith's modified model. The accumulate runoff losses were 64, 32, 30 e 15% from the total rainfall, for Vertissolo 1, Chernossolo, Argissolo e Vertissolo 2, respectively. The relationship between initial runoff and the runoff rate was inversively, independently of the soil surface and rainfall conditions. Increasing rainfall intensity decreases the initial runoff time and increase runoff rate. Smith's modified model provides a better runoff estimated in soils with high soil moisture content.
RESUMO.
Os objetivos deste trabalho foram determinar e modelar o escoamento superficial para solos com diferentes características físicas a partir de diferentes intensidades de chuva. Foram realizadas chuvas simuladas em diferentes solos, no Uruguai. Chuvas artificiais com intensidades de 30, 60 e 120mm h-1 foram aplicadas utilizando-se um simulador estacionário de bicos múltiplos e oscilantes. Em cada solo foram determinados o tempo de início e a taxa de escoamento superficial, além da chuva (quantidade, duração e intensidade), declividade do terreno, matéria seca na superfície e cobertura do solo, densidade (do solo e de partícula), porosidade do solo (macro, micro e total), textura (argila, silte e areia), umidade inicial e saturação do solo. Foi utilizado o modelo modificado de Smith para estimativa do escoamento superficial. As perdas acumuladas por escoamento superficial foram de 64, 32, 30 e 15% do total aplicado para Vertissolo 1, Chernossolo, Argissolo e Vertissolo 2, respectivamente. Há uma relação inversa entre o tempo de início do escoamento e a taxa constante de escoamento superficial, independentemente das condições da superfície do solo e da chuva. Isso está associado à intensidade da chuva, pois quanto mais esta aumentar, menor é o tempo de início do escoamento e maior é a taxa constante de escoamento superficial. O modelo modificado de Smith estima melhor o escoamento superficial sob condições de elevada umidade do solo. MenosABSTRACT.
The objective of this research was to determinate and modeling the runoff for different soils classes based on different simulated rainfall intensities (30, 60 and 120mm h-1) in different soils in Uruguay. A portable rainfall simulator with multiple nozzles was used to simulate different rainfall intensities. On each soil was measured the initial time and rate of runoff, rainfall (total, duration and intensities), direction of slope, crop residue and cover percentage, soil densities (bulk and particle), soil porosity (bulk, macro and micro), textural fractions (clay, silt and sand), initial and saturated soil moisture. The runoff was estimated with Smith's modified model. The accumulate runoff losses were 64, 32, 30 e 15% from the total rainfall, for Vertissolo 1, Chernossolo, Argissolo e Vertissolo 2, respectively. The relationship between initial runoff and the runoff rate was inversively, independently of the soil surface and rainfall conditions. Increasing rainfall intensity decreases the initial runoff time and increase runoff rate. Smith's modified model provides a better runoff estimated in soils with high soil moisture content.
RESUMO.
Os objetivos deste trabalho foram determinar e modelar o escoamento superficial para solos com diferentes características físicas a partir de diferentes intensidades de chuva. Foram realizadas chuvas simuladas em diferentes solos, no Uruguai. Chuvas artificiais com intensidades de 30, 60 e 120mm h-1 foram aplicadas utilizand... Presentar Todo |
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Palabras claves : |
Escoamento superficial; Física do solo; Intensidade da chuva; Rainfall intensity; Rainfall simulator; Runoff; Simulador de chuva; Soil physics. |
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Asunto categoría : |
P10 Recursos hídricos y su ordenación |
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URL : |
http://www.scielo.br/pdf/cr/v39n1/a12v39n1.pdf
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Marc : |
LEADER 03753naa a2200301 a 4500
001 1060737
005 2020-01-31
008 2009 bl uuuu u00u1 u #d
022 $a0103-8478
024 7 $a10.1590/S0103-84782009000100012$2DOI
100 1 $aSPOHR, R.B.
245 $aRunoff modeling from soil physical characteristics in different places in Uruguay. [Modelagem do escoamento superficial a partir das características físicas de alguns solos do Uruguai.]$h[electronic resource]
260 $c2009
500 $aArticle history: Recebido para publicação 11 Decembro 2007 / Aprovado em 20 Agosto 2008.
520 $aABSTRACT. The objective of this research was to determinate and modeling the runoff for different soils classes based on different simulated rainfall intensities (30, 60 and 120mm h-1) in different soils in Uruguay. A portable rainfall simulator with multiple nozzles was used to simulate different rainfall intensities. On each soil was measured the initial time and rate of runoff, rainfall (total, duration and intensities), direction of slope, crop residue and cover percentage, soil densities (bulk and particle), soil porosity (bulk, macro and micro), textural fractions (clay, silt and sand), initial and saturated soil moisture. The runoff was estimated with Smith's modified model. The accumulate runoff losses were 64, 32, 30 e 15% from the total rainfall, for Vertissolo 1, Chernossolo, Argissolo e Vertissolo 2, respectively. The relationship between initial runoff and the runoff rate was inversively, independently of the soil surface and rainfall conditions. Increasing rainfall intensity decreases the initial runoff time and increase runoff rate. Smith's modified model provides a better runoff estimated in soils with high soil moisture content. RESUMO. Os objetivos deste trabalho foram determinar e modelar o escoamento superficial para solos com diferentes características físicas a partir de diferentes intensidades de chuva. Foram realizadas chuvas simuladas em diferentes solos, no Uruguai. Chuvas artificiais com intensidades de 30, 60 e 120mm h-1 foram aplicadas utilizando-se um simulador estacionário de bicos múltiplos e oscilantes. Em cada solo foram determinados o tempo de início e a taxa de escoamento superficial, além da chuva (quantidade, duração e intensidade), declividade do terreno, matéria seca na superfície e cobertura do solo, densidade (do solo e de partícula), porosidade do solo (macro, micro e total), textura (argila, silte e areia), umidade inicial e saturação do solo. Foi utilizado o modelo modificado de Smith para estimativa do escoamento superficial. As perdas acumuladas por escoamento superficial foram de 64, 32, 30 e 15% do total aplicado para Vertissolo 1, Chernossolo, Argissolo e Vertissolo 2, respectivamente. Há uma relação inversa entre o tempo de início do escoamento e a taxa constante de escoamento superficial, independentemente das condições da superfície do solo e da chuva. Isso está associado à intensidade da chuva, pois quanto mais esta aumentar, menor é o tempo de início do escoamento e maior é a taxa constante de escoamento superficial. O modelo modificado de Smith estima melhor o escoamento superficial sob condições de elevada umidade do solo.
653 $aEscoamento superficial
653 $aFísica do solo
653 $aIntensidade da chuva
653 $aRainfall intensity
653 $aRainfall simulator
653 $aRunoff
653 $aSimulador de chuva
653 $aSoil physics
700 1 $aCARLESSO, R.
700 1 $aGARCIA, C.
700 1 $aGARCÍA PRÉCHAC, F.
700 1 $aGARCÍA PETILLO, M.
773 $tCiencia Rural, January 2009, Volume 39, Issue 1, January 2009, Pages 74-81. OPEN ACCESS.
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